So, I was hoping to move to my mule because I love it's name, so I'm getting ready to send my items and gold over there when I began to wonder something. I've already played my max games on this account so here's the question, can I play games on my new main tonight or just to be safe, should I wait until tomorrow?

It is acceptable to play on your mule as well, though the times do reset at 12am CST, and I am in that timezone myself and it's already past. So it's the next day anyhow, so there's no problem what-so-ever for playing with your mule anyhow.

Oh, thanks. Sorry for the trouble, I just wanted to make sure I wasn't doing anything bad. o.o

It's no trouble at all.
I'll be locking this up.

If you have further questions feel free to PM me.